Overview of the EU FP7-project HISTORIC

HISTORIC aims to develop and test complex photonic integrated circuits containing a relatively large number of digital photonic elements for use in e.g. all-optical packet switching. These photonic digital units are all-optical flip-flops based on ultra compact laser diodes, such as microdisk lasers and photonic crystal lasers. These lasers are fabricated making use of the heterogeneous integration of InP membranes on top of silicon on insulator (SOI) passive optical circuits. The very small dimensions of the lasers are, at least for some approaches, possible because of the high index contrast of the InP membranes and by making use of the extreme accuracy of CMOS processing. All-optical flip-flops based on heterogeneously integrated microdisk lasers with diameter of 7.5 mu m have already been demonstrated. They operate with a CW power consumption of a few mW and can switch in 60ps with switching energies as low as 1.8 fJ. Their operation as all-optical gate has also been demonstrated. Work is also on-going to fabricate heterogeneously integrated photonic crystal lasers and all-optical flip-flops based on such lasers. A lot of attention is given to the electrical pumping of the membrane InP-based photonic crystal lasers and to the coupling to SOI wire waveguides. Optically pumped photonic crystal lasers coupled to SOI wires have been demonstrated already. The all-optical flip-flops and gates will be combined into more complex photonic integrated circuits, implementing all-optical shift registers, D flip-flops, and other all-optical switching building blocks. The possibility to integrate a large number of photonic digital units together, but also to integrate them with compact passive optical routers such as AWGs, opens new perspectives for the design of integrated optical processors or optical buffers. The project therefore also focuses on designing new architectures for such optical processing or buffer chips

Ion pairing in model electrolytes: A study via three particle correlation functions

A novel integral equations approach is applied for studying ion pairing in the restricted primitive model (RPM) electrolyte, i. e., the three point extension (TPE) to the Ornstein-Zernike integral equations. In the TPE approach, the three-particle correlation functions $g^{[3]}({\bf r}_{1},{\bf r}_{2},{\bf r}_{3})$ are obtained. The TPE results are compared to molecular dynamics (MD) simulations and other theories. Good agreement between TPE and MD is observed for a wide range of parameters, particularly where standard integral equations theories fail, i. e., low salt concentration and high ionic valence. Our results support the formation of ion pairs and aligned ion complexes.Comment: 43 pages (including 18 EPS figs) - RevTeX 4 - J. Chem. Phys. (in press

Field theory for size- and charge asymmetric primitive model of electrolytes. Mean-field stability analysis and pretransitional effects

The primitive model of ionic systems is investigated within a field-theoretic description for the whole range of size-, \lambda, and charge, Z, ratios of the two ionic species. Two order parameters (OP) are identified, and their relations to physically relevant quantities are described for various values of \lambda and Z. Instabilities of the disordered phase associated with the two OP's are determined in the mean-field approximation. A gas-liquid separation occurs for any Z and \lambda different from 1. In addition, an instability with respect to various types of periodic ordering of the two kinds of ions is found

Equilibrium solvation in quadrupolar solvents

We present a microscopic theory of equilibrium solvation in solvents with zero dipole moment and non-zero quadrupole moment (quadrupolar solvents). The theory is formulated in terms of autocorrelation functions of the quadrupolar polarization (structure factors). It can be therefore applied to an arbitrary dense quadrupolar solvent for which the structure factors are defined. We formulate a simple analytical perturbation treatment for the structure factors. The solute is described by coordinates, radii, and partial charges of constituent atoms. The theory is tested on Monte Carlo simulations of solvation in model quadrupolar solvents. It is also applied to the calculation of the activation barrier of electron transfer reactions in a cleft-shaped donor-acceptor complex dissolved in benzene with the structure factors of quadrupolar polarization obtained from Molecular Dynamics simulations.Comment: Submitted to J. Chem. Phys., 20 pages and 13 figure

Revised and extended analysis in four times ionized xenon Xe V

The atomic-emission spectrum of four times ionized xenon (Xe V) has been observed in the region 500–6700 Å; 233 lines were classified as transition between 5s5p3, 5s25p5d, 5s25p6s with 5s25p2, 5s25p6p and 5s25p4f configurations. Ninty-seven of these lines are reported for the first time. Two new energy level values corresponding to the 5s25p4f configuration have been determined, and we proposed two new values for the previously reported 3D1 and 3G5 energy levels of this configuration. The value of the 5s25p6p 1S0 energy level has also been determined, and we propose a new value for the previously reported 5s25p5d 3F4 energy level. New adjusted values for the previously known levels of the studied configurations are included. Least-squares fitted parametric calculations involving configuration interactions have been carried out to interpret the observed spectrum.Facultad de Ciencias ExactasCentro de Investigaciones Óptica

Revised and extended analysis in four times ionized xenon Xe V

The atomic-emission spectrum of four times ionized xenon (Xe V) has been observed in the region 500–6700 Å; 233 lines were classified as transition between 5s5p3, 5s25p5d, 5s25p6s with 5s25p2, 5s25p6p and 5s25p4f configurations. Ninty-seven of these lines are reported for the first time. Two new energy level values corresponding to the 5s25p4f configuration have been determined, and we proposed two new values for the previously reported 3D1 and 3G5 energy levels of this configuration. The value of the 5s25p6p 1S0 energy level has also been determined, and we propose a new value for the previously reported 5s25p5d 3F4 energy level. New adjusted values for the previously known levels of the studied configurations are included. Least-squares fitted parametric calculations involving configuration interactions have been carried out to interpret the observed spectrum.Facultad de Ciencias ExactasCentro de Investigaciones Óptica

Theory of solvation in polar nematics

We develop a linear response theory of solvation of ionic and dipolar solutes in anisotropic, axially symmetric polar solvents. The theory is applied to solvation in polar nematic liquid crystals. The formal theory constructs the solvation response function from projections of the solvent dipolar susceptibility on rotational invariants. These projections are obtained from Monte Carlo simulations of a fluid of dipolar spherocylinders which can exist both in the isotropic and nematic phase. Based on the properties of the solvent susceptibility from simulations and the formal solution, we have obtained a formula for the solvation free energy which incorporates experimentally available properties of nematics and the length of correlation between the dipoles in the liquid crystal. Illustrative calculations are presented for the Stokes shift and Stokes shift correlation function of coumarin-153 in 4-n-pentyl-4'-cyanobiphenyl (5CB) and 4,4-n-heptyl-cyanopiphenyl (7CB) solvents as a function of temperature in both the nematic and isotropic phase.Comment: 19 pages, 9 figure

Asymmetric Primitive-Model Electrolytes: Debye-Huckel Theory, Criticality and Energy Bounds

Debye-Huckel (DH) theory is extended to treat two-component size- and charge-asymmetric primitive models, focussing primarily on the 1:1 additive hard-sphere electrolyte with, say, negative ion diameters, a--, larger than the positive ion diameters, a++. The treatment highlights the crucial importance of the charge-unbalanced ``border zones'' around each ion into which other ions of only one species may penetrate. Extensions of the DH approach which describe the border zones in a physically reasonable way are exact at high $T$ and low density, $\rho$, and, furthermore, are also in substantial agreement with recent simulation predictions for \emph{trends} in the critical parameters, $T_c$ and $\rho_c$, with increasing size asymmetry. Conversely, the simplest linear asymmetric DH description, which fails to account for physically expected behavior in the border zones at low $T$, can violate a new lower bound on the energy (which applies generally to models asymmetric in both charge and size). Other recent theories, including those based on the mean spherical approximation, have predicted trends in the critical parameters quite opposite to those established by the simulations.Comment: to appear in Physical Review

Coexistence and Criticality in Size-Asymmetric Hard-Core Electrolytes

Liquid-vapor coexistence curves and critical parameters for hard-core 1:1 electrolyte models with diameter ratios lambda = sigma_{-}/\sigma_{+}=1 to 5.7 have been studied by fine-discretization Monte Carlo methods. Normalizing via the length scale sigma_{+-}=(sigma_{+} + sigma_{-})/2 relevant for the low densities in question, both Tc* (=kB Tc sigma_{+-}/q^2 and rhoc* (= rhoc sigma _{+-}^{3}) decrease rapidly (from ~ 0.05 to 0.03 and 0.08 to 0.04, respectively) as lambda increases. These trends, which unequivocally contradict current theories, are closely mirrored by results for tightly tethered dipolar dimers (with Tc* lower by ~ 0-11% and rhoc* greater by 37-12%).Comment: 4 pages, 5 figure